Alessio Cancian
PhD thesis title: Experimental and modeling analyses of performance and degradation in Anion Exchange Membrane Water Electrolyzers
Academic Tutor: Andrea Casalegno
Academic Supervisor: Matteo Zago
PhD cycle: 40° (see all student profiles of the same cycle > LINK)
BSc: Energy Engineering, Politecnico di Milano
MSc: Energy Engineering, Politecnico di Milano
``Pietro Luigi Cavallotti`` Master Thesis Award (2025)
Thesis abstract
My PhD research focuses on Anion Exchange Membrane Water Electrolyzers (AEMWEs), an emerging technology for green hydrogen production powered by renewable electricity. I combine experimental testing and physics-based modeling to investigate the physical phenomena that affect electrolyzer performance, durability, and safety under realistic operating conditions. In particular, I study degradation mechanisms, dynamic operation during startup and shutdown, hydrogen crossover, and electrochemical diagnostic techniques to support the development of more efficient and reliable systems.
Personal interest in my research theme
I chose this topic because I wanted to work on a technology that can contribute to the energy transition in a concrete way. What I find most interesting is the combination of experiments and modeling: I enjoy understanding the physical mechanisms behind complex electrochemical systems and translating experimental observations into deeper insights that can help design better and more durable electrolyzers.
